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61789-51-3 环烷酸钴

环烷酸钴
英文名称：Cobalt Naphthenate
CAS：

61789-51-3

 分子式：C20H34CoO4
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  • 化合物简介
  • 基本信息
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环烷酸钴简介

Cobalt(II) naphthenate is a mixture of cobalt(II) derivatives of naphthenic acids. Cobalt Naphthenate is a cobalt source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). Cobalt naphthenate is the cobalt salt of naphthenic acids. Naphthenic acids are a complex group of carboxylic acids with the general formula C, HZ~+~O~, where n indicates the carbon number and Z specifies the hydrogen deficiency resulting from ring formation. Cobalt naphthenate is thus a member of the metal carboxylates group. All of the metal carboxylate salts are designed to add metals to chemical reactions. They therefore are expected to dissociate into free metal and free acid. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Cobalt Naphthenate is commonly used in various catalysts and catalytic reagents for organic synthesis. These coordination complexes are widely used as oil drying agents for the autoxidative crosslinking of drying oils. Metal naphthenates are not well defined in conventional chemical sense that they are mixtures. They are widely employed catalysts because they are soluble in the nonpolar substrates, such as the alkyd resins or linseed oil. The fact that naphthenates are mixtures helps to confer high solubility. A second virtue of these species is their low cost. A well-defined compound that exhibits many of the properties of cobalt naphthenate is the cobalt(II) complex of 2-ethylhexanoic acid. Often in technical literature, naphthenates are described as salts, but they are probably also non-ionic coordination complexes with structures similar to basic zinc acetate.Cobalt naphthenate is used primarily in unsaturated polyester resins, paint drier applications and rubber adhesion promotion in the tire industry. One characteristic of cobalt naphthenate and other metal carboxylates is that they readily dissociate from an ion pair into free metal and free acid. They are found as partially dissociated products in the ambient environment (i.e., neutral pH). Dissociation is a reversible process and the proportion of dissociated salt is dependent on the pH and pKa (the dissociation constant), which is the pH at which 50% dissociation occurs. In the low pH environment of the digestive tract 3 (e.g., pH 1.2) complete dissociation will occur for these metal carboxylates. The transport and’bioavailability of the metals and acids are determined by their solubility in environmental media and biological fluids which is determined by environmental parameters such as pH. Dissociation is a reversible reaction, splitting the parent compound into two or more chemical species which may be ionic, but are not necessarily so. The processcan be generally represented as:
[RCOO’]x:[M+]-[RCOO-]x + [M’] -[RCOOH], + [M’]
undissociated salt dissociated acid and metal neutral species + ionized metal High pH Low pH The pKa and pH are equal when the metal carboxylate salt is 50% dissociated. The parent compounds, the metal carboxylate salts, are associated ionized molecules. Because the free acid (naphthenic acid) and corresponding free metal (cobalt) have different characteristics (e.g., solubility, adsorption, and toxicity) than the undissociated salt (ion pair), the proportion of dissociation influences the behavior of the substance in the environment.
The catalytic properties of cobalt(II) naphthenates are similar to those of related compounds containing manganese and iron. Such species are sometimes classified as active driers." Active driers are catalysts that feature redox-active metal centers. Such centers promote redox reactions with hydroperoxide-containing intermediates.

环烷酸钴基本信息

中文名称 环烷酸钴 英文名称 Cobalt Naphthenate
中文别名

石油酸钴; 萘酸钴; 石油酸亚钴;

查看更多中文别名 		英文别名

cobalt(2+),naphthalene-2-carboxylate;

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CAS号 61789-51-3 分子式 C20H34CoO4
分子量 397.41500 精确质量 397.17900
PSA 80.26000 LOGP 2.68560

环烷酸钴编号系统

EINECS号 263-064-0

环烷酸钴物化性质

外观与性状：
黄色至棕色树脂质的液体
密度：
0.95
熔点：
140ºC
闪点：
49ºC
折射率：
n20/D 1.4620
储存条件：
2-8ºC

安全信息

安全说明：
S23-S45-S53-S60-S61-S36-S37
危险类别码：
R49; R10; R36/38; R42/43; R50/53; R40
包装等级：
III
危险标志：
GHS02, GHS08
信号词：
Danger
危险性防范说明：
P210; P261; P280; P284; P301 + P310; P370 + P378
危险性描述：
H226; H304; H317; H334

生产方法及用途

用途

主要用于橡胶粘合剂。

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61789-51-3 环烷酸钴
环烷酸钴
CAS号：61789-51-3 分子式：C20H34CoO4 分子量：397.41500
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