| Product name | Lithium Hydride |
|---|
| Product number | - |
|---|---|
| Other names | Lithium hydride |
| Identified uses | For industry use only. |
|---|---|
| Uses advised against | no data available |
| Company | MOLBASE (Shanghai) Biotechnology Co., Ltd. |
|---|---|
| Address | Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road, Xuhui District, Shanghai, China |
| Telephone | +86(21)64956998 |
| Fax | +86(21)54365166 |
| Emergency phone number | +86-400-6021-666 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
Substances and mixtures, which in contact with water, emit flammable gases, Category 1
Skin corrosion, Category 1B
2.2 GHS label elements, including precautionary statements| Pictogram(s) |   |
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H260 In contact with water releases flammable gases which may ignite spontaneously H314 Causes severe skin burns and eye damage |
| Precautionary statement(s) | |
| Prevention | P223 Do not allow contact with water. P231+P232 Handle and store contents under inert gas/.... Protect from moisture. P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. |
| Response | P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. P370+P378 In case of fire: Use ... to extinguish. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/… P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Storage | P402+P404 Store in a dry place. Store in a closed container. P405 Store locked up. |
| Disposal | P501 Dispose of contents/container to ... |
none
3.Composition/information on ingredients 3.1 Substances| Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
|---|---|---|---|---|
| Lithium Hydride | Lithium Hydride | 7580-67-8 | none | 100% |
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaledFresh air, rest. Half-upright position. No mouth-to-mouth artificial respiration. Refer immediately for medical attention.
In case of skin contactRemove contaminated clothes. Put clothes in sealable container. Rinse skin with plenty of water or shower. Refer immediately for medical attention .
In case of eye contactRinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.
If swallowedRinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.
4.2 Most important symptoms/effects, acute and delayedThis material is relatively toxic to people. It is more likely to cause irritation of skin and mucous membrane tissues rather than death. Its effects are primarily acute. A massive exposure to the eyes and by inhalation may be lethal. Those experiencing any ailment of the upper respiratory tract (e.g., bronchitis or pneumonia) are at a greater risk. (EPA, 1998)
4.3 Indication of immediate medical attention and special treatment needed, if necessaryBasic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Monitor for shock and treat if necessary ... Anticipate seizures and treat if necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during treatment ... Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... Cover skin burns with dry sterile dressings after decontamination ... /Lithium and related compounds/
5.Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing mediaUse approved Class D extinguishers or smother with dry sand, dry clay, or dry ground limestone. Do not use carbon dioxide or halogenated extinguishing agents. Do NOT use water. Violent reaction may result.
5.2 Specific hazards arising from the chemicalIn a fire, irritating alkali fumes may form. Lithium hydride can form airborne dust clouds which may explode on contact with flame, heat, or oxidizing materials. Additionally, spontaneous ignition occurs when nitrous oxide and lithium hydride are mixed. Lithium hydride also forms explosive mixtures with liquid oxygen. Contact with heat, moisture or acid causes exothermic reaction and evolution of hydrogen as well as lithium hydroxide. Incompatible with air and moisture, nitrous oxide, strong oxidizers, and liquid oxygen. Lithium hydride may ignite spontaneously in air and should be maintained and handled out of contact with air and moisture. Any contact with nitrous oxide; airborne powders may ignite upon reaching moisture. (EPA, 1998)
5.3 Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary.
6.Accidental release measures 6.1 Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautionsEvacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Cover the spilled material with dry powder.
6.3 Methods and materials for containment and cleaning upWearing butyl rubber gloves, fireproof clothing, face shield and goggles, cover spill with sand. Transfer mixture into a dry plastic bag filled in advance with an inert gas. Carry outdoors for incineration. After burning (if not in a proper incinerator), sprinkle water on the residue for complete destruction. Alternatively, in the fume hood, add butanol slowly to the solid mixture until the reaction ceases. Then carefully add water until all the hydride is destroyed. Let stand until solid settles.
7.Handling and storage 7.1 Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilitiesSeparated from incompatible materials. See Chemical Dangers. Dry. Keep under mineral oil or inert gas. Cool. Store in an area without drain or sewer access.Store in a cool, dry, well-ventilated location. Must be stored in a dry location. Immediately remove and properly dispose of any spilled material.
8.Exposure controls/personal protection 8.1 Control parameters Occupational Exposure limit valuesRecommended Exposure Limit: 10 Hr Time-Weighted Avg: 0.025 mg/cu m.
Biological limit valuesno data available
8.2 Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3 Individual protection measures, such as personal protective equipment (PPE) Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protectionWear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protectionWear dust mask when handling large quantities.
Thermal hazardsno data available
9.Physical and chemical properties| Physical state | White or bluish transparent lump or powder |
|---|---|
| Colour | Gray cubic crystals or powder, hygroscopic |
| Odour | Odorless ... |
| Melting point/ freezing point | 680ºC |
| Boiling point or initial boiling point and boiling range | 850(分解) |
| Flammability | Combustible Solid that can form airborne dust clouds which may explode on contact with flame, heat, or oxidizers.Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Many reactions may cause fire or explosion. See Chemical dangers |
| Lower and upper explosion limit / flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | 200°C (USCG, 1999) |
| Decomposition temperature | 850°C |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | Reacts with water (NIOSH, 2016) |
| Partition coefficient n-octanol/water (log value) | no data available |
| Vapour pressure | 0 mm Hg at 20°C (EPA, 1998) |
| Density and/or relative density | 0.82 |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
no data available
10.2 Chemical stabilityDarkens rapidly on exposure to light.
10.3 Possibility of hazardous reactionsLithium hydride is a flammable solid and is dangerous when wet.Dust explosion possible if in powder or granular form, mixed with air.LITHIUM HYDRIDE is a strong reducing agent. Th esolid may decompose violently in contact with most oxidizing materials. It reacts exothermically with water to form caustic lithium hydroxide and hydrogen gas; the hydrogen may ignite. May ignite spontaneously in moist air. Mixtures with liquid oxygen are explosive. Ignites on contact with dinitrogen oxide [Mellor, 1967, vol. 8, suppl. 2.2, p. 214].
10.4 Conditions to avoidno data available
10.5 Incompatible materialsReacts with the lower alcohols, carboxylic acids, chlorine and ammonia at 400°C to liberate hydrogen.
10.6 Hazardous decomposition productsThermally unstable. Decomp at 1009 deg F (400°C).
11.Toxicological information Acute toxicity- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
no data available
Serious eye damage/irritationno data available
Respiratory or skin sensitizationno data available
Germ cell mutagenicityno data available
Carcinogenicityno data available
Reproductive toxicityno data available
STOT-single exposureno data available
STOT-repeated exposureno data available
Aspiration hazardno data available
12.Ecological information 12.1 Toxicity- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
no data available
12.3 Bioaccumulative potentialno data available
12.4 Mobility in soilno data available
12.5 Other adverse effectsno data available
13.Disposal considerations 13.1 Disposal methods ProductThe material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
14.Transport information 14.1 UN Number| ADR/RID: UN1414 | IMDG: UN1414 | IATA: UN1414 |
| ADR/RID: LITHIUM HYDRIDE |
| IMDG: LITHIUM HYDRIDE |
| IATA: LITHIUM HYDRIDE |
| ADR/RID: 4.3 | IMDG: 4.3 | IATA: 4.3 |
| ADR/RID: unknown | IMDG: unknown | IATA: unknown |
| ADR/RID: no | IMDG: no | IATA: no |
no data available
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codeno data available
15.Regulatory information 15.1 Safety, health and environmental regulations specific for the product in question| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Lithium Hydride | Lithium Hydride | 7580-67-8 | none |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Not Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Creation Date | Aug 16, 2017 |
|---|---|
| Revision Date | Aug 16, 2017 |
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
购物车
获取报价
投诉建议
0
