12069-00-0 硒化铅(II)

硒化铅(II)

英文名称:LEAD SELENIDE
CAS:

12069-00-0

分子式:PbSe
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  • 化合物简介
  • 基本信息
  • 编号系统
  • 物化性质
  • 安全信息

硒化铅(II)简介

Lead selenide (PbSe), or lead(II) selenide, a selenide of lead, is a semiconductor material. It forms cubic crystals of the NaCl structure; it has a direct bandgap of 0.27eV at room temperature. (Note that incorrectly identifies PbSe and other IV–VI semiconductors as indirect gap materials.) It is a grey crystalline solid material.
It is used for manufacture of infrared detectors for thermal imaging, operating at wavelengths between 1.5–5.2µm. It does not require cooling, but performs better at lower temperatures. The peak sensitivity depends on temperature and varies between 3.7–4.7µm.; Single crystal nanorods and polycrystalline nanotubes of lead selenide have been synthesized via controlled organism membranes. The diameter of the nanorods were approx. 45nm and their length was up to 1100nm, for nanotubes the diameter was 50nm and the length up to 2000nm.
Lead selenide nanocrystals embedded into various materials can be used as quantum dots, for example in nanocrystal solar cells.
Lead selenide is a thermoelectric material. The material was identified as a potential high temperature thermoelectric with sodium or chlorine doping by Alekseva and co-workers at the A.F. Ioffe Institute in Russia. Subsequent theoretical work at Oak Ridge National Laboratory, USA predicted that its p-type performance could equal or exceed that of the sister compound, lead telluride. Several groups have since reported thermoelectric figures of merit exceeding unity, which is the characteristic of a high performance thermoelectric.
The mineral clausthalite is a naturally occurring lead selenide.
It may be formed by direct reaction between its constituent elements (lead and selenium).

硒化铅(II)基本信息

中文名称 硒化铅(II) 英文名称 LEAD SELENIDE
中文别名

硒化铅;

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英文别名

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CAS号 12069-00-0 分子式 PbSe
分子量 286.16000 精确质量 287.89300
PSA 0.00000 LOGP -0.64910

硒化铅(II)编号系统

MDL号 MFCD00016273
EINECS号 235-109-4
PubChem号 24855368

硒化铅(II)物化性质

外观与性状:
灰色粉末和片,无气味
密度:
8.1 g/cm3
熔点:
1065ºC

安全信息

安全说明:
S22; S26; S28; S36/37/39; S45
危险类别码:
R20/22; R33
危险品运输编码:
UN 3288
危险类别:
6.1(a)
包装等级:
II
危险品标志:
Xn
危险性描述:
H301 + H331; H302 + H332; H360Df; H373; H410
信号词:
Danger
危险性防范说明:
P201; P260; P280; P304 + P340 + P312; P308 + P313
危险标志:
GHS06, GHS08, GHS09
硒化铅(II)
CAS号:12069-00-0 分子式:PbSe 分子量:286.16000

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